介绍：
质子海绵也就是1,8-双二甲氨基萘。因为空间位阻效应，它是一种有亲核性的强碱。它还参与蛛网形-6,9-C2B8H14和选择酰氯的反应。它还是一种有效的H+清除剂。
用途：
由于空间位阻效应而具有弱亲核性的强碱。
质子海绵可以用来合成C-取代t-BuNH-8,9-R,R′-nido-7,8,9-C3B8H9 (R,R′=H,H; MeH; Me,Me; Ph,H 和Ph,Ph)三碳内酯化合物。它还可以用来制备饱和铱氟烷基（氢化物）复合体。
1,8-Bis(dimethylamino)naphthalene is a very strong base with weak nucleophilic character due to steric effects.
Proton-sponge can be used in the synthesis of C-substituted t-BuNH-8,9-R,R′-nido-7,8,9-C3B8H9 (R,R′ = H,H; MeH; Me,Me; Ph,H and Ph,Ph) tricarbollide compounds. It was also used in the preparation of saturated fluoroalkyl(hydrido) complexes of Iridium.
相关属性
| CAS编号 | 20734-58-1 |
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| 敏感性 | 对空气、光线敏感 |
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| 熔点 | 48 °C |
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| 沸点 | 145 °C/4 mmHg |
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| 溶解性 | Soluble in methanol, and chloroform. Insoluble in water.Soluble in organic solvents |
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| 储存温度 | 2-8°C储存,避光,充氩 |
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| Reaxys-RN | 396782 |
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| MDL号 | MFCD00003920 |
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| 分子量 | 214.31 |
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| 分子式 | C14H18N2 |
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| 品牌 | 阿拉丁 |
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| PubChem CID | 88675 |
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